Application of CIDNP to the Research on the Mechanism of Free Radical Reactions 化学诱导动态核极化(CIDNP)在光诱导自由基反应机理研究中的应用
In nonpolar solvent, benzene, 1,4-biradical intermediates are formed directly, which lead to the observation of strong CIDNP effects. 在非极性溶液中,直接形成了1,4&双自由基中间体,在产物中产生了极化效应。
The polarity of solvent disfavored the produce of triplet carbonyl compounds, restraining the CIDNP polarizations. 此外,强极性溶剂CD3CN不利于羰基化合物三线态的产生,因此从一定程度上抑制了CIDNP极化信号的产生。
And Chemically Induced Dynamic Nuclear Polarization ( CIDNP) is one of the most powerful means to study free radical reactions and structures of the intermediates. 而化学诱导动态核极化(CIDNP)技术是研究自由基反应及反应中间体结构的有效手段之一。
CIDNP and its applications to photochemistry CIDNP及其在光化学中的应用