Study on the Erosion Process of Amorphous Hydrocarbon Films with Retarding Field Analyzer Chrono-amperometric Determination of Hydrogen Peroxide with Calixarene Modified Carbon Fiber Electrode 非晶碳氢膜刻蚀率与离子能量分布函数关系的研究用杯芳烃膜修饰碳纤维电极计时电流法测定过氧化氢
Microwave irradiation assisted rapid synthesis of calixarene ester derivatives 微波辐射促进杯芳烃酯类衍生物的快速合成
This thesis describes the syntheses and complexation properties of some novel calixarene aza derivatives and polymers. 为此,本论文设计并合成了在下沿同时引入多个含氮的软配位基团的杯芳烃衍生物及其聚合物。
Application of Calixarene and Its Derivatives in Life Science 杯芳烃及其衍生物在生命科学中的研究进展
The Synthesis and Application of P-tert-butyl-type Calixarene Compounds 对叔丁基杯芳烃类化合物的合成及其应用
Design and Synthesis of Calixarene Molecules Containing Functional Group 含硫功能基的杯芳烃分子的设计与合成
Chrono-amperometric Determination of Hydrogen Peroxide with Calixarene Modified Carbon Fiber Electrode current reversal chronopotentiometry 用杯芳烃膜修饰碳纤维电极计时电流法测定过氧化氢
The synthesis and properties of calixarene-porphyrin compounds are reviewed. 本工作综述了杯芳烃-卟啉化合物的合成及性质。
Progress in study of polymers containing calixarene 含杯芳烃聚合物研究进展
The recent advances in supramolecular chemistry research are reviewed in this paper, mainly including molecular recognition and assembly of synthetic receptors ( hosts), such as crown ether, cryptand, lariat ether, bis ( crown ether) s, cyclodextrin, calixarene, and cyclophane. 综述超分子化学研究的最新进展,包括冠醚、穴醚、臂式冠醚、双冠醚、环糊精、杯芳烃和环番等人工合成受体(主体)的分子识别与分子组装的研究概况。
Novel Calixarene Derivatives Containing Pyrazole has been synthesized recently and characterized by 1H NMR and elemental analysis. 本文合成了一个含吡唑环的杯芳烃衍生物,并经1HNMR和元素分析确证结构。
A Comparison Study between Liquid-Liquid Extraction and Liquid Membrane Transport of Silver by Calixarene Derivatives 杯芳烃衍生物液-液萃取和液膜传输银的对比研究及机理探讨
In chapter 1, a review of calixarene structures, syntheses, chemical modifications, properties and applications were presented. 第一章对杯芳烃的结构、合成、化学修饰、性质、应用,做了简要的概括和评述。
The study of calixarene membrane electrode 杯芳烃膜电极研究
Studies on graft reactions of calixarene derivatives with polystyrene 杯芳烃衍生物与聚苯乙烯的接枝反应
In this paper the progress of the coordination and supramolecular chemistry of iron with calixarene based cyclic ligands in recent years is introduced, and their coordination structures and supramolecular mechanisms discussed. 介绍了近年来杯芳烃对铁的配位及其超分子化学的研究进展,讨论了杯芳烃对铁的配位结构及其超分子作用机理。
The more interest which calixarene has aroused is due to its molecular structure and physical chemistry property. 杯芳烃作为继冠醚、环糊精之后的第三代主体分子,以其特有的分子结构特征和物理化学性质吸引了人们的目光。
Progress in Research and Application of Calixarene Derivatives In Fluorescence Analysis by Host-guest Recognition 杯芳烃衍生物在主-客体识别荧光分析中的应用及进展
Selective transport of metal ions across liquid membrane can be achieved by using calixarene derivatives with recognition groups. 藉杯芳烃衍生物的识别作用可以实现对金属离子的选择性液膜传输。
The fluorination yield reached 81.2% when calixarene was chosen as phase transfer catalyst. 氟化反应中采用杯芳烃作为相转移催化剂,收率达81.2%;
According to the conductance results, the reactions between 4-tert-butyl-calix [ 4] arene and amines proceed in two steps. First, a proton transfer from calixarene to amine. 电导测定表明在乙腈溶液中脂肪胺与对叔丁基杯[4]芳烃间的反应分两步进行:首先胺从杯芳烃得到一个质子生成胺正离子和杯负离子,然后离子再进一步包合。
Study on the Supramolecular Inclusion Complex of Fullerenes with p tert butyl Calixarene Benzyl Ether 球烯与对叔丁基杯[8]芳烃苯醚形成超分子包合物的研究
This paper introduces the origin of supra-molecular chemistry and the research on Calixarene. 扼要介绍了超分子化学的起源,评述了杯芳烃的研究进展,包括杯芳烃的由来、性质、合成及应用等。
Various calixarene compounds and their derivatives have been obtained one after another. 各种新型杯芳烃化合物及其衍生物相继被合成出来。
However, we noticed that in supramolecular chemistry, research on the third generation host molecule calixarene mainly focused on design and synthesis of structures, as well as related metal complexation abilities. Report on its self-assembly behavior is limited. 然而,我们注意到,在超分子化学领域,对第三代主体分子杯芳烃的研究主要着重于其结构的设计和合成,及其对金属离子络合的研究,对其自身的自组装行为还很少报道。
Reported one-step synthesis of calixarene is explored and the conditions are improved to synthesize tert-butyl calix [ 4] arene at high yield. 本文对文献报道的杯芳烃一步合成法的反应条件进行了摸索和改进,以高产率合成了对叔丁基杯[4]芳烃,为本课题工作的开展提供了便利。
Cyclodextrin and calixarene, as the second and third generation supramolecular hosts, represent two important research directions in supramolecular chemistry, which have been widely applied in the molecular recognition and self-assembly. 这其中作为第二和第三代大环主体分子的环糊精和杯芳烃代表着超分子化学的两个重要研究方向,在分子识别及组装体构筑中得到了广泛的应用。
In this paper, amphiphilic calixarene derivatives were synthesized using p-tert-butyl-phenol as an original reactant and some their applications in analytical chemistry were studied. 本文以对叔丁基苯酚和甲醛为原料,合成了两亲性的杯芳烃衍生物,并研究了它在分析化学中的应用。
In this thesis, we focus on the self-assembly behavior of amphiphilic calixarene in the mixture of water and ethanol, as well as related preparation of functional hybrid materials made of silica and gold nanoparticles. 本文的研究重点就是双亲性杯芳烃在水/乙醇体系中的自组装,及相应的含氧化硅和金纳米粒子的杂化纳米组装体的制备及其功能材料的研究。
Many kinds of calixarene derivatives with versatile properties can be derived by modifying the up-rim and the down-rim of the calixarenes. 通过对杯芳烃的上沿、下沿和桥碳亚甲基的修饰,能得到很多种功能各异的杯芳烃衍生物。