The relationship between bond valence and bond covalency has been investigated by a semiempirical method. 用一种半经验方法研究了固体材料中键电荷与键共价性的关系。
And why did he call it polar covalency? 为什么要称它为极性共价呢?
So you can see that polar covalency is a tendency towards ionic bonding. 所以你看得出极性共价就是,趋向离子键的。
The ordering of the magnitude for bond covalency is La-O 共价性的大小次序为La-O
The results obtained indicate the influence of the host lattice, radius of positive ion and the covalency of the Pr 3+-O 2-bond on the spectral character. 探讨了基质晶格、阳离子半径、Pr3+-O2-键的共价性等因素对光谱性质的影响;
The results of calculation show that the bonds between lanthanum and coordination atoms have certain extent covalency. 结果表明,镧与配位原子间的键具有一定程度的共价性。
In this paper, the relationship that the average covalency reduction factor N and the crystal field parameter D q alter with temperature from the equation of solid has been found. Therefore the temperature dependence spectrum in Zn 1-x Mn xSe may be explained satisfactorily. 该文从固态物质的物态方程出发,找到了根据共价效应修正因子N和晶场参数Dq随温度变化的关系,从而满意地解释了Zn1-xMnxSe光谱的温度移位。
Investigation of Covalency and Spectrum Shifts in 3 d Transition-metal Compounds 3d过渡晶体化学键共价性和光谱位移研究
The IR spectra of styrene-acrylic acid copolymer-supported neodymium complexes were investigated. The complexes possess a structure of bidentate carboxylate groups and the Nd-O bond in the complexes is rich in covalency. 红外光谱研究表明,苯乙烯-丙烯酸共聚物载体-钕络合物具有双配位的羧酸根结构,Nd-O键富有共价性。
The results indicate that the intensity parameters Ω_2 and Ω_4 increase with the increase of GeO_2 contents. It suggests that the symmetry becomes lower, the band of Eu and O atoms becomes stronger and the covalency increases. 结果显示强度参量Ω2与Ω4随着GeO2量的增加而增加,表明材料的对称性降低,Eu-O键强增加,共价性增加。
Influence of Susceptibilities and Covalency on Sn~ ( 4+) and I~-Mossbauer isomer shifts 共价和极化对~(119)Sn、~(129)I穆斯堡尔谱位移的影响
It is found that Li ions have more space to move, and its covalency is very strong. 分析发现,Li离子在晶胞内有更大活动空间,共价性很强。