Recent Progress in Application of N-Heterocyclic Carbene Metal Complexes to Ketone Hydrosilylation N-杂环卡宾金属配合物在酮硅氢加成反应中的应用新进展
Despite a lot of researchers have paid much attention to this reaction, there have been very few reports on the hydrosilylation of ferrocenylsilanes. 尽管人们对这一反应进行了大量研究,但有关二茂铁硅烷的硅氢化反应却少见文献报道。
Hydrosilylation of alkenes catalyzed by Rh ( PPh_3)_3Cl in ionic liquids: influence of medium on addition reaction 离子液体对Rh(PPh3)3Cl催化烯烃硅氢加成反应的影响
This review presented the preparation, characterization and mechanism of supported platinum catalysts for hydrosilylation reaction of alkenes in recent years. 本文综述了近年来烯烃硅氢加成反应固载铂催化剂的制备、表征及其催化反应机理;
The effects of temperature, the quantity of catalyst used, and reactant feed rate on hydrosilylation was discussed. 考察了温度、催化剂用量、加料速率等因素对苯乙烯与甲基二氯硅烷硅氢加成反应的影响。
Progress in Transition Metal-Phosphorus Complexes for Hydrosilylation Reaction 过渡金属膦配合物在硅氢化反应中的应用研究
In this dissertation, Ir-catalyzed asymmetric hydrogenation, asymmetric transfer hydrogenation and asymmetric hydrosilylation of quinoline derivatives have been studied. 本论文研究了铱催化喹啉衍生物的不对称氢化、不对称转移氢化和不对称硅氢化反应。
Synthesis and Characterization of Silica-Supported Chitosan-Platinum Complex for Catalytic Hydrosilylation SiO2负载壳聚糖络合铂配合物的合成和表征及其催化硅氢加成反应的性能
Synthesis of MCM-41-Supported Sulfur, Phosphine Rhodium and Platinum Complexes and Their Catalytic Properties in Hydrosilylation MCM-41负载硫、膦铑和铂配合物的合成及催化烯烃硅氢化性能研究
Study of Hydrosilylation of Long-chain α-Alkene 长链α-烯烃的硅氢加成反应研究
The effects on the condition of hydrosilylation and the conversion of hydrogen-containing silicone oil were studied. The key intermediate and the structure of the product was characterized by IR, and its surface activity was determined. 研究了硅氢加成反应条件对含氢硅油转化率的影响、用IR谱图表征了关键中间体及产物的结构、测定了产物的表面特性。
It was then reacted with low hydrogen containing silicone oil via hydrosilylation to produce epoxy-containing polyether silicone. 再与低含氢硅油进行硅氢加成反应,合成出环氧聚醚改性聚甲基硅氧烷;
In this paper, a novel photosensitive silicone acrylate was synthesized from hydrogen-containing silicone fluid ( PHDS) and multifunctional organic acrylate ( TPGDA) by a very convenient route of the direct hydrosilylation, using chloroplatinic acid as the catalyst. 以含氢硅油和三缩丙二醇二丙烯酸酯(TPGDA)为原材料,氯铂酸为催化剂,采用硅氢加成方法直接合成了光敏性有机硅丙烯酸酯。
The application of free radical reaction to hydrosilylation 自由基反应在硅氢加成中的应用
Studies on the hydrosilylation catalyzed by chloroplatinic acid-triphenyl-phosphine system 氯铂酸-三苯基膦体系催化硅氢加成反应的研究氢溴酸西酞普兰的合成
Study on hydrosilylation of acetylene and methyldichlorosilane& preparation of platinum matal colloid and Its Catalytic Behavior 乙炔和甲基二氯硅烷的硅氢加成反应研究&Ⅰ.金属铂胶体的制备及其催化性能
Studies on the Chiral Structure of Thiazolidine Ligands and Their Application to Asymmetric Hydrosilylation of Acetophenone 噻唑烷类配体的手性结构及其在催化苯乙酮不对称硅氢化反应中的应用研究
Study on Hydrosilylation Mechanism Catalyzed by Polystyrene Bound Platinum Complex 聚苯乙烯-铂络合物催化硅氢加成反应机理的研究血卟啉铂络合物的合成
Recent advances in asymmetric hydrosilylation of prochiral carbonyl compounds catalyzed by chiral transition metal complexes are reviewed in this paper with 47 references. 评述了近年来手性金属配合物催化的前手性羰基化合物的不对称硅氢化反应研究进展。
During the last decade new hydrosilylation catalysts, predominantly homogenous and heterogenous transition metal complexes have been developed. 近年出现了许多新的硅氢加成反应催化剂,主要是指过渡金属化合物的均相和多相催化剂。
During the hydrosilylation reaction, the thermal polymerization of MMA also happened. 在硅氢加成反应的同时伴随有MMA的热聚合反应发生。
Application of Hydrosilylation in Preparing and Modification of Polymers 硅氢加成反应在聚合物制备及改性中的应用
Study on Catalytic Mechanism of Hydrosilylation of Unsaturated Esters by Electronic Spectroscopy 电子光谱法研究不饱和酯类硅氢化的催化作用机理
Hydrosilylation Catalyzed with Ruthenium Complex in Ionic Liquid 离子液体中钌配合物催化硅氢化反应研究
γ-Bromopropyl methyl dichlorosilane monomer ( A) was synthesized by hydrosilylation of allyl bromide with methyl dichlorosilane. 通过烯丙基溴的硅氢化反应,合成了γ-溴丙基甲基二氯硅烷单体(A);
Results showed that the colloidal platinum was stable and active for the hydrosilylation. 结果表明,此保护剂存在下的铂胶体对乙炔和三氯硅烷的硅氢加成反应有良好的反应活性和稳定性。
The research of this topic is actual meaning and academic value to improve the development of the hydrosilylation of ketones catalyzed by metal. 因此具有很好的理论研究和工业应用价值,可进一步推进金属催化酮硅氢加成反应研究的发展。
In addition, the influence of hydrosilylation catalyst on hydrosilylation addition effect was also studied. It is found that Karsted catalyst has better hydrosilylation addition effect than platinum dioxide. 研究了二氧化铂催化剂和Karsted催化剂对硅氢加成效果的影响,发现与二氧化铂硅氢加成催化剂相比,Kasted催化剂具有更好的硅氢加成效果,且反应时间短。