A mild and high efficient method to prepare glycidyl nitrate by selective nitration of glycidol with dinitrogen pentoxide as the nitrating agent was developed. 研究了一种五氧化二氮为硝化剂,选择性硝化缩水甘油合成缩水甘油硝酸酯的温和、高效方法。
Aminothiazole and its homologues can be nitrated in the same way, using a double excess of nitrating mixture. 用二倍过量的混合硝化剂,能将氨基噻唑及其同系物以同样的方法硝化。
The types, technology and characteristics of the "green" nitration for preparing nitric esters using dinitrogen pentoxide as the nitrating agent were introduced. 前言:简要介绍以五氧化二氮为硝化剂制备硝酸酯的“绿色”硝化反应的类型、工艺及特点。
According to the practice of nitrochlorobenzene production in our plant, the effects of composition of mixed acid, temperature and stir on nitrating reaction. 根据我厂硝基氯苯的生产实践,概述了混酸组成、温度、搅拌等因素对硝化反应的影响。
A heavy yellow poisonous oily explosive liquid obtained by nitrating glycerol; used in making explosives and medically as a vasodilator. 一种重的、黄色有毒油状爆炸性液体,由甘油硝化制成,用于制炸药,医学上用作血管舒张药。
In some more complex cases, secondary amines can be nitrated directly with nitrating mixtures. 在某些复杂的情况下,仲胺能用混合硝化剂直接硝化。
More expensive nitrating agents may be used. 还可应用较贵的硝化剂。
Nitroglycerin is obtained by nitrating glycerol. 硝化甘油是经过硝化丙三醇得来的。
Study on Novel Nitrating System for the Preparation of Nitrocellulose 利用新型硝化体系制备硝化纤维素的工艺研究
Centrifuge, nitrating, for gun-cotton manufacture complete equipment for making plaster medical absorbent cotton 制造火药棉丝用硝化离心机医用脱脂药棉生产成套设备
N-nitro-2,4,6-Trichloroaniline was synthesized from aniline with acetyl nitrate as nitrating agent. 以苯胺为原料,以乙酰硝酸酯为硝化剂,合成了N硝基2,4,6三氯苯胺。
The orthogonal design was used in the optimum synthesis of cyclohexyl nitrate with the mixture of nitric acid and acetic anhydride as the nitrating agent of cyclohexanol. 以硝酸-醋酐混合物为环己醇的硝化剂,利用正交试验设计描述了硝酸环己酯的优化合成。
If the nitrating agent is the O3-NO2 system, free aromatic cationic radicals would be formed and the spin density of each carbon atom is the determining factor of product distribution. O3-NO2体系的硝化反应中,产生了游离的芳烃正离子自由基(ArH~+),其产物分布决定于ArH~+上的自旋密度分布。
Clean Nitrating Agent Dinitrogen Pentoxide and Its Application in Nitration 绿色硝化剂五氧化二氮及其在硝化反应中的应用
Nitration of Toluene with a Clean Nitrating Agent-Dinitrogen Pentoxide 绿色硝化剂五氧化二氮对甲苯的硝化研究
Factors influencing the product yield are discussed, such as nitrating agents, reductive agents, reaction temperature, reaction time, have been investigated. 考察了酰化反应温度、酰化反应时间、硝化剂种类、水解反应时间、还原剂种类、甲酸用量等因素对各步反应收率的影响。
By the use of the new nitrating agent, the use of concentrated sulfuric acid was avoided and the reaction was environmental friendly with high atom economy. 该方法通过改变硝化剂,不仅成功地避免了浓硫酸的使用,而且提高了原子经济性,具有良好的环境效益。
In this paper, we study the nitrating and analytic conditions of red ink. 本文对可食印刷红色油墨的消解过程,测定方法及分析条件进行了系统研究。
Alkyl benzenes and halo benzenes were nitrated with TFAA-NH_4NO_3 as nitrating reagent in the two acidic ionic liquids as solvents and catalysts. 以制备的两种酸性离子液体为溶剂和催化剂,TFAA和NH4NO3的组合为硝化剂,研究了烷基苯、卤苯和六亚甲基四胺在不同条件下硝化的收率和选择性。
With the nitrating agent such as nitric-acid-sulphuric acid, this paper studies the nitration of ( 1,3-bi [ 3 '-chloro-aniline]-2,4,6-tri nitro benzene) which is an intermediary of a new heat& resistant explosive. 本文用硝硫混酸作硝化剂,对1,3&二[3′-氯苯氨基]-2,4.6-三硝基苯,这个新型耐热炸药的中间体进行了硝化研究。
The produce obtained in the two kinds of nitrating agents above was a mixture of crystal keto RDX and RDX. 在上述两种硝化剂中得到的产物为RDX酮与RDX的晶体混合物。
Study on the Reaction Form of Urea and Nitrourea in Nitrating Agents 几种硝化剂中脲和硝基脲的反应形式(Ⅰ)加料方式的研究
The article based on the special microglass reactor as the core, established the microreaction system, which used in the aromatic nitration research. ( 1) Using nitric acid as nitrating agents, we detailedly studied on the nitration process of toluene in the microreactor system. 本文以特殊的微玻璃反应器为核心,完成微反应系统的建立,应用于芳烃硝化研究。(1)在微反应系统内,重点探索以硝酸为硝化剂甲苯硝化工艺研究。