Firstly β elimination from 1-octanol to octanal and later radical process from octanal to octanoic acid were plausible reaction mechanism. 该反应的机理为首先从正辛醇到辛醛的β消除,随后从辛醛到正辛酸的自由基历程。
In this paper, water-oxalic acid-TOA ( octanol) is used as the experimental system, and TOA, octanal as complexing agent, diluent respectively. 选择草酸稀溶液为萃取对象,采用三辛胺(TOA)为络合剂,正辛醇为稀释剂,开展了TOA萃取草酸的机理研究。