Racemization is found with optically active substrates. 发现旋光基质有外消旋作用。
Sodium oiethyl dithiocarbamate Amino-acid Racemization Dating 二乙基硫代氨基甲酸钠
The first study of the age of Yuanmou Man by the method of amino acid racemization geochronology 用氨基酸测年法对元谋人年代的初步研究
Determination of Degree of Racemization of Aspartic Acid in Dentine Comparison of Chiral Capillary Gas Chromatography with High Performance Liquid Chromatography 牙本质中天冬氨酸消旋化程度的测定&手性毛细管气相色谱法与高效液相色谱法的比较
The result showed that racemization was not observed when the pH value was 7 and the reaction temperature was lower than 37 ° C. 发现在严格控制pH为7.0,反应温度不高于37°C的条件下,并不出现消旋作用。
Studies on Racemization in Thioester Condensation 硫酯缩合反应中的消旋问题研究
Acetylized Racemization Process and Kinetics of D-penicillamine D-青霉胺酰化消旋工艺及动力学研究
Spontaneous Racemization of α-Bromo-( o-chloro) phenylacetic Acid During the Resolving Process α-溴代邻氯苯乙酸拆分过程中的自消旋现象研究
The water in carboxylic acid decreased the rate of racemization. 在羧酸溶剂中有水存在会降低消旋反应速率。
The theoretical basis of the racemization of amino acids in oceanic sediments 海洋沉积物中氨基酸外消旋反应的理论基础
The mechanism of the racemization was discussed. 同时也论述了氨基酸消旋的反应机理。
OBJECTIVE: To study the process of acetylized racemization of D-penicillamine in the acidic condition. 目的研究D-青霉胺在酸性条件下进行酰化外消旋的工艺。
Studies on Racemization and Resolution of p-Hydroxyphenylglycine 对羟基苯甘氨酸的消旋及拆分研究
Amino acid racemization dating of Holocene shell deposits from coastal area of Fujian 福建沿海全新世贝壳沉积物的氨基酸外消旋年代测定
Analysis of Racemization Products of Synthetic Heptapeptide by Reversed Phase High Performance Liquid Chromatography/ Mass Spectrometry 反相高效液相色谱与质谱联用分析合成七肽的消旋产物
In the reaction mechanism of unimolecular nucleophilic substitution ( SN1), it can produce carbocations which can easily lead to the racemization of the products. 由于单分子亲核取代反应(SN1)经过了碳正离子中间体的历程,所以得到的产物是外消旋的。
Moreover, the racemization of LLA blocks can be enhanced with long reaction time, high temperature, and the addition of comonomers. 而且L-LA的消旋作用随着反应时间的延长、反应温度和共聚单体GA的增加而增强。
To our surprise, racemization happened during the cyclization in method one. 令人意外的是,方法一环合过程中发生消旋现象。
The ee values of the final products were very close to those of α-hydroxy ketones, which indicated that no racemization occurred in the substitution. 最终产物的ee值与中间体α-羟基酮十分接近,表明在所发生的亲核取代反应中基本没有消旋化得现象发生。
This incredible discovery led to our in-depth study on their mechanism of racemization. 这一不可思议的发现促使我们对其消旋化机理进行了深入地研究。
The transesterification and the racemization can also result in lower crystallinity, which are further verified by DSC and WAXD measurements. 酉旨交换和外消旋作用都将降低聚合物结晶度,DSC和XRD结果的进一步验证了个结论。